4-(Carboxymethoxy)anilinium bromide
نویسنده
چکیده
In the title hydro-bromide salt, C(8)H(10)NO(3) (+)·Br(-), the positive charge resides on the N atom and the carboxyl -CO(2) end of the cation carries an H atom. In the crystal, N-H⋯Br, O-H⋯Br and N-H⋯O hydrogen bonds link the cations and anions, forming a ladder propagating along the a axis.
منابع مشابه
On the Order-Disorder Phase Transformation of Anilinium Halides. III. High Temperature Phase Crystal Structure of Anilinium Bromide, C6H5NH3®Br. An X-ray and Neutron Diffraction Study
The crystal structure of the high temperature phase of anilinium bromide, CeH5NH3®Br , was studied by X-ray and neutron diffraction at T = 343 K . The refinement supports disordered positions of the —NH3® group. A split-atom model is proposed which includes disorder of the benzene ring. The thermal parameters, hydrogen bond distances, and other experimental data (NMR, N Q R , inelastic neutron ...
متن کامل4-Methoxyanilinium bromide
The title compound, C(7)H(10)NO(+)·Br(-), consists of almost planar 4-methoxy-anilinium cations, wherein the O atom lies 0.049 (3) Å out of the plane formed by the non-H atoms, and a Br(-) anion. Strong N-H⋯Br and N-H⋯(Br,Br) hydrogen bonding contributes to the stability of the crystal structure and links the cations and anions into a three-dimensional network.
متن کاملOn the Order-Disorder Phase Transformation of Anilinium Halides. IV. The Crystal Structure of the Low Temperature Phase of Anilinium Bromide, C6H5NHs©Br©. A Neutron Diffraction Study
für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...
متن کاملTris(N,N-dimethylanilinium) hexabromidostannate(IV) bromide
In the title compound, (C8H12N)3[SnBr6]Br, the anilinium N atom of one of the three unique cations exhibits flip-flop disorder with an 0.60:0.40 occupancy ratio. In the crystal, N-H⋯Br hydrogen bonds link the N,N-di-methyl-anilinium cations and both Br(-) anions and [SnBr6](2-) dianions into a layered arrangement parallel to (001).
متن کامل2-Nitroanilinium bromide
The title compound, C(6)H(7)N(2)O(2) (+)·Br(-), is isomorphous with 2-nitro-anilinium chloride and contains an characteristic intra-molecular N-H⋯O hydrogen bond, forming an S(6) motif. Inter-molecular N-H⋯Br hydrogen bonds occur in the crystal structure. Two zigzag chains of C(2) (1)(4) motifs extend along the b-axis direction. These primary chain motifs inter-sect like a double helix structur...
متن کامل